Optimization of perilla seed oil extraction using supercritical CO2
Main Article Content
Keywords
Perilla frutescens; Linolenic acid; Tocopherol
Abstract
This work studied the extraction of perilla oil from perilla seeds using supercritical carbon dioxide, which is valued for its high omega-3 content. Response surface methodology was used to investigate the optimum conditions of perilla oil extraction at pressures of 200, 225, and 250 bar and temperatures of 40°C, 50°C, and 60°C. The fatty acid composition was also investigated. The optimal condition was obtained at 60°C under a pressure of 218 bar. Under this extraction condition, the predicted measures of oil yield (%), acid value, peroxide value, iodine value, saponification value, total phenolic content, DPPH (IC50), ABTS (IC50), and tocopherol were: 37.00%, 1.22 mg KOH/g, 0.94 mEq O2/kg, 205.00 g I2/100 g, 196.90 mg KOH/g, 12.14 mg GAE/100 g, 10.93 mg/mL, 154.86 mg/mL, and 604.58 mg/kg, respectively. In addition, gas chromatography analysis indicated that perilla seed oil was primarily composed of linolenic acid (56.94–58.02%), with a total polyunsaturated fatty acid content of 75.49–76.47%, while saturated fatty acids and monounsaturated fatty acids constituted 10.53–11.11% and 13.00–13.52% of the total fatty acids, respectively.
References
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Garcia, V. A., Lemos, C. O., Mantovani, D., Corazza, M., Zanoelo, E., Silva, C., & Filho, L. (2015). EFFECT OF OIL EXTRACTION WITH SUPERCRITICAL CO2 AND ORGANIC SOLVENTS ON ANTIOXIDANT CAPACITY AND TOTAL PHENOLIC CONTENT OF Mucuna MEAL. Latin American Applied Research - An international journal, 45, 125-131. https://doi.org/10.52292/j.laar.2015.386
Gokbulut, I., Bilenler, T., & Karabulut, I. (2013). Determination of Chemical Composition, Total Phenolic, Antimicrobial, and Antioxidant Activities of Echinophora tenuifolia Essential Oil. International Journal of Food Properties, 16(7), 1442-1451. https://doi.org/10.1080/10942912.2011.593281
Hao, L., Lv, C., Cui, X., Yi, F., & Su, C. (2021). Study on biological activity of perilla seed oil extracted by supercritical carbon dioxide. LWT, 146, 111457. https://doi.org/https://doi.org/10.1016/j.lwt.2021.111457
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Jang, H., & Park, K. (2020). Omega-3 and omega-6 polyunsaturated fatty acids and metabolic syndrome: A systematic review and meta-analysis. Clinical Nutrition, 39(3), 765-773. https://doi.org/https://doi.org/10.1016/j.clnu.2019.03.032
Jiao, Z., Ruan, N., Wang, W., Guo, M., Han, S., & Cheng, J. (2021). Supercritical carbon dioxide co-extraction of perilla seeds and perilla leaves: experiments and optimization. Separation Science and Technology, 56(3), 617-630. https://doi.org/10.1080/01496395.2020.1728320
Joshi, A., Sharma, A., Pandey, D. P., & Bachheti, R. (2015). Physico-chemical properties of Perilla frutescens seeds. Der Pharma Chemica, 7, 35-41.
Jung, D. M., Yoon, S. H., & Jung, M. Y. (2012). Chemical Properties and Oxidative Stability of Perilla Oils Obtained From Roasted Perilla Seeds As Affected by Extraction Methods [https://doi.org/10.1111/j.1750-3841.2012.02965.x]. Journal of Food Science, 77(12), C1249-C1255. https://doi.org/https://doi.org/10.1111/j.1750-3841.2012.02965.x
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